As a .NET developer, you must be familiar with CodePlex. There are some great projects there - I like to surf around and see what other developers are doing, and try some of the products. I've found a lot of things from CodePlex useful, so here are my top 3...
The patterns & practices team at Microsoft has several project on CodePlex. A lot of software factories - but the main one is the Enterprise Library which is a huge help, when you want something done without having to re-invent a lot of stuff... Also listen to this .NET Rocks podcast with David Hayden, explaining the Enterprise Library in more detail.